Pfaltz, Andreas and Baeza, Alejandro. (2009) Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Enamines. Chemistry - A European Journal, 15 (10). pp. 2266-2269.
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Official URL: http://edoc.unibas.ch/dok/A5253839
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Abstract
Optically active tertiary amines are readily prepared by iridium-catalyzed asymmetric hydrogenation of unfunctionalized enamines (see scheme). The best enantioselectivities with >90 % ee were obtained with N-aryl- and N-benzyl-substituted enamines with a terminal double bond. The hydrogenation of enamines derived from cyclic ketones, which has not been reported yet with other catalysts, gave enantiomeric excesses of up to 87 %.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz) |
|---|---|
| UniBasel Contributors: | Pfaltz, Andreas |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 0947-6539 |
| e-ISSN: | 1521-3765 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 10 Apr 2017 13:35 |
| Deposited On: | 22 Mar 2012 14:07 |
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