Constable, Edwin C. and Hermann, Bianca A. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Scherer, Lukas J.. (2005) 2,2′:6′,2″-Terpyridine-4′(1′H)-thione : a missing link in metallosupramolecular chemistry. New Journal of Chemistry, 29 (11). pp. 1475-1481.
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Official URL: http://edoc.unibas.ch/dok/A5248872
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Abstract
The compound 2,2`: 6`,2 ``-terpyridine-4`(1`H)-thione 1 has been prepared and structurally characterised; in both the solid state and in solution, the thione tautomer is dominant. Compound 1 is a key entry into 4`-sulfur-functionalised tpy ligands and a representative alkylation with an electrophilic Frechet dendrimer is presented and the structural characterisation of the new ligand 4 reported. Oxidation of 1 yields bis(2,2`: 6`,2 ``-terpyridin- 4`-yl) disulfide 2 which is a novel homoditopic tpy ligand and which forms a tetranuclear [ 4 + 4] iron (II) metallomacrocycle. Structural characterisation of 2 and preliminary data for the iron complex are presented.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
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| UniBasel Contributors: | Constable, Edwin Charles and Housecroft, Catherine Elizabeth |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1144-0546 |
| e-ISSN: | 1369-9261 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 10 May 2017 09:28 |
| Deposited On: | 22 Mar 2012 14:07 |
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