Laurenczy, Gabor and Faure, Matthieu and Vieille-Petit, Ludovic and Suss-Fink, Georg and Ward, Thomas R.. (2002) Mechanistic in situ High-Pressure NMR Studies of Benzene Hydrogenation by Supramolecular Cluster Catalysis with [(η6-C6H6)(η6-C6Me6)2Ru3(μ3-O)(μ2-OH)(μ2-H)2][BF4]. Advanced Synthesis and Catalysis, 344 (10). pp. 1073-1077.
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Official URL: http://edoc.unibas.ch/dok/A5254455
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Abstract
In situ high-pressure NMR spectroscopy of the hydrogenation of benzene to give cyclohexane, catalysed by the cluster cation [(η6-C6H6) (η6-C6Me6)2Ru3(μ3-O)(μ2-OH)(μ2-H)2]+2, supports a mechanism involving a supramolecular host-guest complex of the substrate molecule in the hydrophobic pocket of the intact cluster molecule.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Ward, Thomas R. R. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1615-4150 |
| e-ISSN: | 1615-4169 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 24 Apr 2017 14:26 |
| Deposited On: | 22 Mar 2012 14:08 |
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