Bonazzi, S. and Binaghi, M. and Fellay, C. and Wach, J. Y. and Gademann, K.. (2010) Synthetic Studies on the Sporolides : Exploration of the Enediyne Route. Synthesis, 4. pp. 631-642.
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Abstract
Synthetic studies towards the construction of the cyclopenta[a]indene fragment of the heptacyclic marine metabolite sporolide are reported based on a hypothetical biosynthesis. The key step of this biogenetic proposal includes a Bergman cyclization of an enediyne precursor. The enediyne target of this synthetic study was prepared by Sonogashira cross-coupling of two fragments, of which the cyclopentane fragment was prepared from cyclopentenone, Morita-Baylis-Hillman reaction, and enantioselective Sharpless dihydroxylation.
Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Organische Chemie (Gademann) |
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UniBasel Contributors: | Gademann, Karl |
Item Type: | Article, refereed |
Article Subtype: | Research Article |
Publisher: | Georg Thieme |
ISSN: | 0039-7881 |
e-ISSN: | 1437-210X |
Note: | Publication type according to Uni Basel Research Database: Journal article |
Language: | English |
Identification Number: |
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edoc DOI: | |
Last Modified: | 02 Feb 2017 10:51 |
Deposited On: | 14 Sep 2012 06:56 |
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