Liniger, Marc and Gschwend, Björn and Neuburger, Markus and Schaffner, Silvia and Pfaltz, Andreas. (2010) Unprecedented Reactivity of Iridium(I) Secondary Phosphine Oxide Complexes: Formation of P-Coordinated Phosphinate Complexes by P−Aryl Bond Cleavage. Organometallics, 29 (22). pp. 5993-5958.
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Official URL: http://edoc.unibas.ch/dok/A5841370
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Abstract
Aryl−iridium(III) hydride complexes with a P-coordinated phosphinate were formed from [Ir(cod)Cl]2 and secondary phosphine oxide−oxazoline ligands under basic conditions. The structure of these complexes, whose formation involved C−P cleavage, was assigned by X-ray analysis and NMR spectroscopy.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz) |
|---|---|
| UniBasel Contributors: | Pfaltz, Andreas |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 0276-7333 |
| e-ISSN: | 1520-6041 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 10 Apr 2017 13:23 |
| Deposited On: | 14 Sep 2012 07:00 |
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