Lörtscher, Emanuel and Cho, Clara J. and Mayor, Marcel and Tschudy, Meinrad and Rettner, Charles and Riel, Heike. (2011) Influence of the Anchor Group on Charge Transport through Single-Molecule Junctions. ChemPhysChem, 12 (9). pp. 1677-1682.
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Official URL: http://edoc.unibas.ch/dok/A5843761
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Abstract
The molecule–metal coupling in molecular junctions is investigated at the single-molecule level by anchoring a phenyl ring, using either thiol (Figure, A) or isocyanide (Figure, B) linkers, to two gold electrodes of a mechanically controllable break-junction. The transport properties of the single-molecule junctions are recorded while repeatedly forming and breaking the molecular junction. Thiol linkage results in a 50 % larger molecular-level broadening compared to isocyano linkage.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor) |
|---|---|
| UniBasel Contributors: | Mayor, Marcel |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 1439-4235 |
| e-ISSN: | 1439-7641 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 05 Apr 2017 12:49 |
| Deposited On: | 14 Sep 2012 07:01 |
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