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Synthesis of new serine-based phosphinooxazoline ligands and iridium complexes for asymmetric hydrogenations

Franzke, Axel and Voss, Felix and Pfaltz, Andreas. (2011) Synthesis of new serine-based phosphinooxazoline ligands and iridium complexes for asymmetric hydrogenations. Tetrahedron, 67 (24). pp. 4358-4363.

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Official URL: http://edoc.unibas.ch/dok/A5849077

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Abstract

A series of serine-based phosphinooxazoline ligands was synthesized and the corresponding iridum complexes were successfully applied in the asymmetric hydrogenation of various unfunctionalized olefines and acetophenone-N-phenyl-imine. The results show that these new derivatives are useful substitutes for the standard tert-leucine-derived PHOX ligands.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz)
UniBasel Contributors:Pfaltz, Andreas
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Elsevier
ISSN:0040-4020
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:10 Apr 2017 09:47
Deposited On:14 Sep 2012 07:02

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