Clemens, M. and Gillingham, Dennis and Ward, Thomas R. and Hilvert, Donald. (2011) An Artificial Metalloenzyme for Olefin Metathesis. Journal of the Chemical Society, Chemical Communications, 47 (44). pp. 12068-12070.
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Official URL: http://edoc.unibas.ch/dok/A6002023
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Abstract
A Grubbs-Hoveyda type olefin metathesis catalyst, equipped with an electrophilic bromoacetamide group, was used to modify a cysteine-containing variant of a small heat shock protein from Methanocaldococcus jannaschii. The resulting artificial metalloenzyme was found to be active under acidic conditions in a benchmark ring closing metathesis reaction.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward) |
|---|---|
| UniBasel Contributors: | Ward, Thomas R. R. and Gillingham, Dennis |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 0022-4936 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 03 May 2017 08:15 |
| Deposited On: | 08 Nov 2012 16:10 |
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