Schramm, York and Barrios-Landeros, Fabiola and Pfaltz, Andreas. (2013) Discovery of an Iridacycle Catalyst with Improved Reactivity and Enantioselectivity in the Hydrogenation of Dialkyl Ketimines. Chemical Science, 4. pp. 2760-2766.
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Abstract
Catalytically active iridacycles are formed by cyclometalation of acetophenone imines with Ir-PHOX complexes under hydrogen atmosphere. These complexes show unusually high reactivity and enantioselectivity in the hydrogenation of alkyl methyl ketimines. The structure of the cyclometalated imine has a strong effect on the conversion and enantiomeric excess.
| Faculties and Departments: | 05 Faculty of Science 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz) |
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| UniBasel Contributors: | Pfaltz, Andreas |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 2041-6520 |
| e-ISSN: | 2041-6539 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 10 Apr 2017 08:57 |
| Deposited On: | 31 Jan 2014 09:51 |
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