Miyatake-Ondozabal, Hideki and Bannwart, Linda M. and Gademann, Karl. (2013) Enantioselective total synthesis of virosaine A and bubbialidine. Chemical Communications, 49 (19). pp. 1921-1923.
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Abstract
The first enantioselective total syntheses of virosaine A and bubbialidine are described. Key transformations include the formation of a tetracyclic intermediate via an intramolecular aza-Michael addition, generation of a N-hydroxy-pyrrolidine through a Cope elimination and an intramolecular [1,3]-dipolar cycloaddition to generate a complex 7-oxa-1-azabicyclo[3.2.1]octane ring system.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Organische Chemie (Gademann) |
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| UniBasel Contributors: | Gademann, Karl |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 0022-4936 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 28 Nov 2016 15:21 |
| Deposited On: | 27 Feb 2014 15:45 |
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