Schmid, Fabian and Bernasconi, Maurizio and Jessen, Henning J. and Pfaltz, Andreas and Gademann, Karl. (2014) Catalytic Enantioselective Total Synthesis of (–)-Pyridovericin. Synthesis, 46 (07). pp. 864-870.
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Official URL: http://edoc.unibas.ch/dok/A6337611
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Abstract
The first enantioselective catalytic total synthesis of (–)-pyridovericin is reported. The key steps involve a modified HWE reaction under aqueous conditions and an asymmetric iridium-catalyzed hydrogenation. This resulted in a highly modular and stereoselective approach that delivered the target natural product in high yield and stereoselectivity.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Synthetische organische Chemie (Pfaltz) |
|---|---|
| UniBasel Contributors: | Pfaltz, Andreas and Gademann, Karl and Schmid, Fabian |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Georg Thieme |
| ISSN: | 0039-7881 |
| e-ISSN: | 1437-210X |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: | |
| Last Modified: | 10 Apr 2017 08:47 |
| Deposited On: | 06 Feb 2015 09:59 |
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