Masillamani, Appan Merari and Osella, Silvio and Liscio, Andrea and Fenwick, Oliver and Reinders, Federica and Mayor, Marcel and Palermo, Vincenzo and Cornil, Jerome and Samori, Paolo. (2014) Light-induced reversible modification of the work function of a new perfluorinated biphenyl azobenzene chemisorbed on Au (111). Nanoscale, 6 (15). pp. 8969-8977.
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Official URL: http://edoc.unibas.ch/dok/A6337621
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Abstract
We describe the synthesis of a novel biphenyl azobenzene derivative exhibiting: (i) a protected thiol anchoring group in the [small alpha]-position to readily form self-assembled monolayers (SAMs) on Au surfaces; and (ii) a terminal perfluorinated benzene ring in the [small omega]-position to modify the surface properties. The design of this molecule ensured both an efficient in situ photoswitching between the trans and cis isomers when chemisorbed on Au(111),
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Molecular Devices and Materials (Mayor) |
|---|---|
| UniBasel Contributors: | Mayor, Marcel |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | RSC Publishing |
| ISSN: | 2040-3364 |
| e-ISSN: | 2040-3372 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 30 Mar 2017 13:01 |
| Deposited On: | 06 Feb 2015 09:59 |
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