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Biotinylated Metathesis Catalysts: Synthesis and Performance in Ring Closing Metathesis

Kajetanowicz, Anna and Chatterjee, Anamitra and Reuter, Raphael and Ward, Thomas R.. (2014) Biotinylated Metathesis Catalysts: Synthesis and Performance in Ring Closing Metathesis. Catalysis Letters, 144 (3). pp. 373-379.

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Official URL: http://edoc.unibas.ch/dok/A6338942

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Abstract

Nine biotinylated Grubbs–Hoveyda and Grubbs-type metathesis catalysts were synthesized and evaluated in ring closing metathesis reactions of N-tosyl diallylamine and 5-hydroxy-2-vinylphenyl acrylate. Their catalytic activity in organic- and aqueous solvents was compared with the second generation Grubbs–Hoveyda catalyst. The position of the biotin-moiety on the N-heterocyclic carbene was found to critically influence the catalytic activity of the corresponding ruthenium-based catalysts.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie > Bioanorganische Chemie (Ward)
UniBasel Contributors:Chatterjee, Anamitra and Reuter, Raphael and Ward, Thomas R. R.
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Springer
ISSN:1011-372X
e-ISSN:1572-879X
Note:Publication type according to Uni Basel Research Database: Journal article
Last Modified:24 Apr 2017 10:05
Deposited On:06 Mar 2015 07:44

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