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Diastereoselective and Highly Enantioselective Henry Reactions using C(1)-Symmetrical Copper(II) Complexes

Chougnet, Antoinette and Zhang, Guoqi and Liu, Kegang and Haeussinger, Daniel and Kaegi, Andreas and Allmendinger, Thomas and Woggon, Wolf-D.. (2011) Diastereoselective and Highly Enantioselective Henry Reactions using C(1)-Symmetrical Copper(II) Complexes. Advanced Synthesis and Catalysis, 353 (10). pp. 1797-1806.

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Official URL: http://edoc.unibas.ch/dok/A6438692

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Abstract

Catalytic Henry reactions of aliphatic aldehydes and prochiral nitro compounds were investigated using copper(II) complexes of 14 C(1)-symmetrical ligands derived from (1R,2R)(-)-diaminocyclohexane. beta-Nitro alcohols with syn:anti ratios of up to 5.7 and excellent ee values for both diastereosimers were obtained.
Faculties and Departments:05 Faculty of Science > Departement Chemie > Chemie
05 Faculty of Science > Departement Chemie > Chemie > Nuclear Magnetic Resonance (Häussinger)
UniBasel Contributors:Woggon, Wolf-Dietrich and Chougnet, Antoinette and Häussinger, Daniel
Item Type:Article, refereed
Article Subtype:Research Article
Publisher:Wiley
ISSN:1615-4150
e-ISSN:1615-4169
Note:Publication type according to Uni Basel Research Database: Journal article
Identification Number:
Last Modified:29 Mar 2017 14:41
Deposited On:06 Nov 2015 10:21

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