Constable, Edwin C. and Housecroft, Catherine E. and Neuburger, Markus and Schaffner, Silvia and Shardlow, Ellen J.. (2007) Bis[mu(2)-bis(diphenylphosphino)methane]-1 : 2 kappa P-2 : P `;2 : 3 kappa P-2 : P `-dichlorido-1 kappa Cl,3 kappa Cl-triangulo-trigold(I) hexafluorophosphate. Acta Crystallographica Section E: Structure Reports Online, 63 (6). M1698-U1084.
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Abstract
In the title compound, [Au3Cl2(C25H22P2)(2)](PF6), the cation possesses a triangular Au-3 core [Au-Au distances 3.1525 (4), 3.2770 (4) and 3.1922 (4) angstrom], two sides of which are bridged by dppm ligands [dppm = bis(diphenylphosphino) methane]. One phenyl group is disordered over two positions in a 0.65:0.35 ratio. The structure of the cation is compared with those in three other salts reported previously.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) |
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| UniBasel Contributors: | Constable, Edwin Charles |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | International Union of Crystallography |
| ISSN: | 1600-5368 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 12 Apr 2017 07:14 |
| Deposited On: | 26 Jan 2016 07:53 |
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