Constable, Edwin C. and Frantz, R. and Housecroft, Catherine E. and Lacour, J. and Mahmood, A.. (2004) Chiral induction in a ribose-decorated metallostar through intrinsic and interionic diastereomeric interactions. Inorganic Chemistry, 43 (16). pp. 4817-4819.
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Abstract
A ribose-functionalized bpy ligand has been prepared and shown to give modest diastereomeric excesses of Lambda-[FeL3](2+) complexes; interconversion of Delta and Lambda cations is relatively fast, and in CHCl3, the favored complexes with Delta- or Lambda-TRISPHAT counterions are homochiral, (Delta(+)Delta(-)) or (Delta(+)Lambda(-)). In the case of the Delta-TRISPHAT salt, a single diastereomer is observed (de greater than or equal to 96Publisher = AMER CHEMICAL SOC
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Constable) 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Anorganische Chemie (Housecroft) |
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| UniBasel Contributors: | Constable, Edwin Charles |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 0020-1669 |
| e-ISSN: | 1520-510X |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 12 Apr 2017 08:52 |
| Deposited On: | 03 Feb 2016 09:30 |
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