Fesser, Petra and Iacovita, Cristian and Wäckerlin, Christian and Vijayaraghavan, Saranyan and Ballav, Nirmalya and Howes, Kara and Gisselbrecht, Jean-Paul and Crobu, Maura and Boudon, Corinne and Stöhr, Meike and Jung, Thomas A. and Diederich, François. (2011) Visualizing the product of a formal cycloaddition of 7,7,8,8-tetracyano-p-quinodimethane (TCNQ) to an acetylene-appended porphyrin by scanning tunneling microscopy on Au(111). Chemistry - A European Journal, 17 (19). pp. 5246-5250.
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Abstract
Click it: The applicability of a formal [2+2] cycloaddition between electron-rich alkynes and electron-deficient TCNQ on an atomically clean Au(111) surface was demonstrated by scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS). At low coverage, monomeric and self-assembled dimeric species of the initial compounds as well as of the reaction product, a TCNQ-conjugated porphyrin, could be visualized.
| Faculties and Departments: | 05 Faculty of Science > Departement Physik > Physik |
|---|---|
| UniBasel Contributors: | Jung, Thomas A. |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Wiley |
| ISSN: | 0947-6539 |
| e-ISSN: | 1521-3765 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 18 Sep 2017 10:35 |
| Deposited On: | 27 Oct 2016 09:50 |
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