Jahnke, Ann Christin and Pröpper, Kevin and Bronner, Catherine and Teichgräber, Jörg and Dechert, Sebastian and John, Michael and Wenger, Oliver S. and Meyer, Franc. (2012) A New Dimension in Cyclic Coinage Metal Pyrazolates: Decoration with a Second Ring of Coinage Metals by Inter-ring Metallophilic Interactions. Journal of the American Chemical Society, 134 (6). pp. 2938-2941.
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Abstract
When pyrazolate ligands with thioether chelate arms are used in cyclic coinage metal pyrazolates [Au(μ-pz)]n, the inner gold ring can be framed with an outer silver ring to give novel heterometallic double-crowned complexes [AuAg(μ-Lx)(BF4)]4. They feature short intramolecular in-plane Ag–Au interactions, are stable as octanuclear species in solution, and show promising luminescence properties.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Chemie > Anorganische Chemie (Wenger) |
|---|---|
| UniBasel Contributors: | Wenger, Oliver and Jahnke, Ann Christin and Bronner, Catherine |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | American Chemical Society |
| ISSN: | 0002-7863 |
| e-ISSN: | 1520-5126 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 05 Jan 2017 10:51 |
| Deposited On: | 05 Jan 2017 10:51 |
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