Yang, Lei and Melot, Romain and Neuburger, Markus and Baudoin, Olivier. (2017) Palladium(0)-catalyzed asymmetric C(sp3)–H arylation using a chiral binol-derived phosphate and an achiral ligand. Chemical Science, 8 (2). pp. 1344-1349.
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Abstract
The first efficient palladium(0)-catalyzed enantioselective C(sp 3 )–H activation reaction using a catalytic chiral base and an achiral phosphine ligand is reported. Fine-tuning the binol-derived phosphoric acid pre-catalyst and the reaction conditions was found to be crucial to achieve high levels of enantioselectivity for a variety of indoline products containing both tri- and tetrasubstituted stereocenters.
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie 05 Faculty of Science > Departement Chemie > Chemie > Synthetische Chemie (Baudoin) |
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| UniBasel Contributors: | Yang, Lei and Melot, Romain and Neuburger, Markus and Baudoin, Olivier |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 2041-6520 |
| e-ISSN: | 2041-6539 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Language: | English |
| Identification Number: |
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| edoc DOI: | |
| Last Modified: | 01 Feb 2017 12:39 |
| Deposited On: | 01 Feb 2017 12:38 |
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