Renggli, Kasper and Sauter, Nora and Rother, Martin and Nussbaumer, Martin G. and Urbani, Raphael and Pfohl, Thomas and Bruns, Nico. (2017) Biocatalytic atom transfer radical polymerization in a protein cage nanoreactor. Polymer Chemistry, 8 (14). pp. 2133-2136.
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Official URL: http://edoc.unibas.ch/56109/
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Abstract
Incorporation of the ATRP-catalyzing enzyme horseradish peroxidase (HRP) into the cavities of the group II chaperonin thermosome is demonstrated. The resulting nanoreactor was used to polymerize an acrylate under ARGET ATRP conditions. The confined space within the protein cage results in poly(ethylene glycol) methyl ether acrylate (PEGA) with lower molecular weights (poly(styrene)-apparent M-n = 4400 g mol(-1)) as well as narrower molecular weight distributions (D = 1.08) compared to polymerizations with the free ATRPase (M-n = 43 700 g mol(-1) and a D of 1.23).
| Faculties and Departments: | 05 Faculty of Science > Departement Chemie > Former Organization Units Chemistry > Biophysikalische Chemie (Pfohl) |
|---|---|
| UniBasel Contributors: | Pfohl, Thomas |
| Item Type: | Article, refereed |
| Article Subtype: | Research Article |
| Publisher: | Royal Society of Chemistry |
| ISSN: | 1759-9954 |
| e-ISSN: | 1759-9962 |
| Note: | Publication type according to Uni Basel Research Database: Journal article |
| Identification Number: |
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| Last Modified: | 18 Sep 2017 08:35 |
| Deposited On: | 18 Sep 2017 08:35 |
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